Search Results (176)

A high concentration of fluoride (F⁻) in drinking water is harmful and is a serious concern worldwide due to its toxicity and accumulation in the human body. There are various sources of fluoride (F⁻) and divergent pathways to enter into groundwater sources. High F⁻ incidence in groundwater was reported in Raigarh district of Central India in a sedimentary (Gondwana) aquifer system. The present study investigates the hydrogeochemistry of groundwater in the Tamnar area of Raigarh district to understand the plausible cause(s) of high F⁻ concentration, especially the source(s) and underlying geochemical processes. Groundwater samples, representing pre-monsoon (N = 83), monsoon (N = 20), and post-monsoon (N = 81) seasons, and rock samples (N = 4) were collected and analyzed. The study revealed that (i) groundwater with high F⁻ concentration occurs in the Barakar Formation, which has a litho-assemblage of feldspathic sandstones, shales, and coal, (ii) high F⁻ concentration is mainly associated with Na-Ca-HCO₃, Na-Ca-Mg-HCO₃, and Na-Mg-Ca-HCO₃ types of groundwater, (iii) the F⁻ concentration increases as the ratio of Na⁺ and Ca²⁺ increases (Na⁺: Ca²⁺, concentration in meq/l), (iv) F⁻ has significant positive correlation with Na⁺ and SiO₂, and significant negative correlation with Ca²⁺, Mg²⁺, HCO₃⁻, and TH, and (v) high F⁻ concentration in groundwater is found in deeper wells. Micas and clay minerals, occurring in the feldspathic sandstones and intercalated shale/clay/coal beds, possibly form an additional source for releasing F⁻ in groundwater. Feldspar dissolution coupled with anion (OH⁻ or F⁻) and cation (Ca²⁺ for Na⁺) exchange are probably the dominant geochemical processes taking place in the study area. The higher residence time and temperature of groundwater in deeper aquifers also play a role in enhancing the dissolution of fluorine-bearing minerals. Systematic hydrogeochemical investigations are recommended in the surrounding area having a similar geologic setting in view of the potential health risk to a large population. Full article

Spatio-temporal analysis of rainfall trends in a watershed is an effective tool for sustainable water resources management, as it allows for an understanding of the impacts of these changes at the watershed scale. The objective of the present study is to analyze the impacts of climate change on the availability of surface water resources in the Nakanbe–Wayen watershed over the period from 1981 to 2020. The analysis was conducted on in situ rainfall data collected from 14 meteorological stations distributed throughout the watershed and completed with CHIRPS data. Ten precipitation indices, recommended by the ETCCDI (Expert Team on Climate Change Detection and Indices), were calculated using the RClimDex package. The results show changes in the distribution of annual precipitation and an increasing trend in annual precipitation. At the same time, a trend towards an increase in the occurrence and intensity of extreme events was also observed over the last 4 decades. In light of these analyses, it should be emphasized that the increase in precipitation observed in the Nakanbe–Wayen watershed is induced by the increase in the occurrence and intensity of events, as a trend towards an increase in persistent drought periods (CDD) is observed. This indicates that the watershed is suffering from water scarcity. Water stress and water-related hazards have a major impact on communities and ecosystems. In these conditions of vulnerability, the development of risk-management strategies related to water resources is necessary, especially at the local scale. This should be formulated in light of observed and projected climate extremes in order to propose an appropriate and anticipated management strategy for climate risks related to water resources at the watershed scale. Full article

Conducting an accurate hydrological water balance at the regional and country-wide scales is paramount to assessing available water resources and adequately allocating them. One of the main components of these balances is the anthropogenic recharge of groundwater either intentionally, through managed aquifer recharge (MAR), or unintentionally, where infiltration from dams and dykes can play a significant role. In Spain, proper management of water resources is critical due to the arid to semiarid conditions prevalent in most of the territory and the relevance of water resources for maintaining a robust agricultural sector. Previous work estimated country-wide recharge from MAR at 150 to 280 Mm³/year. Recently, water authorities pointed out that, according to hydrological water balances, the total unintentional recharge volume from water courses may exceed 500 Mm³/year. The present research aims to present a new inventory of transverse structures (also referred to as small dams and dykes) in Spain and use it to estimate country-wide unintentional recharge. The inventory, compiled by the Spanish Ministry for the Ecological Transition and the Demographic Challenge, has 27,680 structures and includes construction and impoundment characteristics, which allow for estimating the wet perimeter and the infiltration area. To this end, structural data from the inventory were crossed through map algebra in a GIS environment with thematic layers, such as lithology, permeability, the digital elevation model, the transverse structures’ wetted area, the average groundwater levels, and a clogging correction factor. Two analytical formulas to compute infiltration from small dams and dykes were tested. The resulting volume of unintentional recharge from transverse structures ranges between 812.5 and 2716.6 Mm³/year. The comparison against regional and national water balances suggests that the lowest value of the range (i.e., 812.5 Mm³/year) is probably the most realistic. Anthropogenic recharge from MAR and transverse structures is likely in the range of 1012.5–1514.8 Mm³/year. This rough figure can help close the hydrological balance at the national and river basin levels and contribute to calibrating regional models. Furthermore, they provide an order of magnitude for anthropogenic recharge at a national scale, which is difficult to obtain. Full article

Environmental flows are defined as the flow required into a stream to maintain the river’s ecosystem. The notion of Environmental Flow Allocation (EFA) ensures that a sufficient amount of water is delivered to the stream to maintain ecological integrity. The objective of this study is to examine environmental flows and determine the best acceptable strategy for providing flows into the river in the Lower Tapi Basin. To achieve this objective, daily discharge data from three sites, Ukai (period 1975–2020), Motinaroli (period 1990–2021), and Ghala (period 1995–2005) were collected and analyzed using the Tennant, Tessman, variable monthly flow (VMF), and Smakhtin methodologies. A comparative analysis was carried out on all three sites using the four methodologies. The Tessman and VMF approaches have a strong connection with the computed environmental flow requirements (EFR), according to the results. The calculated EFR was found to be in the range of 30–35% of mean annual flows (MAF). The maximum EFR found at station Ghala is about 54.5% of MAF according to the Tessman method. Such research will help to prevent future degradation of the river by supplying flow in accordance with the EFR, and it will also be used by stakeholders and policymakers to allocate water to preserve the ecosystem. Full article

Climate classifications supply climate visualization with inference about general vegetation types. The Köppen classification system of thermal classes and an arid class is widely used, but options are available to strengthen climate change detection. For this study, I incorporated temperature and aridity information into all climate classes to isolate climate change, added a hypertropical class to better detect warming and drying in tropical zones, and developed a consistent ruleset of thermal classes with one temperature variable for streamlined application, yet maintained primary Köppen thermal classes. I compared climate currently to 6000 years ago (ka; Mid-Holocene) and 22 ka (Last Glacial Maximum) worldwide. Growing degree days > 0 °C was the most efficient variable for modeling thermal classes. Climate classes based on growing degree days matched 86% of Köppen thermal classes. Current climate shared 80% and 23% of class assignments with the Mid-Holocene and Last Glacial Maximum, respectively, with dry conditions shifting to the tropical and hypertropical classes under current climate. Contributing to our understanding of global environmental change, this classification demonstrated that the hypertropical class experienced the greatest change in area since 6 ka and the second greatest change in area since 22 ka, and the greatest increase in percentage arid classes during both intervals. The added hypertropical class with aridity information delivered sensitive detection of warming and drying for relevant climate classes under climate change. Full article

Consumption of fish containing elevated levels of radionuclides can lead to undesirable health effects for consumers. People in the Singida Municipality harvest fish from lakes and ponds of granite rocks which are linked with hazardous radioisotopes that may be bio-concentrated by fishes they consume. Currently, no study has ascertained the levels of radioisotopes in fish from these environments. This study was carried out to analyse the radioactivity levels of ²²⁶Ra, ²²⁸Ra and ⁴⁰K isotopes in order to assess the radiological risk associated with Tilapia fish consumption and its environment in Singida Municipality. Some 51 samples, which included water (20), sediment (20), Nile tilapia (8) and Manyara tilapia (3), were randomly sampled and composited; then, they were analysed using a high-purity germanium (HPGe) detector, between May and June 2022. The results revealed that (i) the activity levels of ²²⁸Ra were below the detection limit for fish and water samples, while in sediment, the combined activity of ²²⁸Ra was within the acceptable international levels; (ii) the mean activity concentrations of ²²⁶Ra and ⁴⁰K in all other samples were within the recommended levels; (iii) the activities of radionuclides in the samples analysed were high in sediments, followed by fish, and lastly water; (iv) the bioaccumulation results show that only ⁴⁰K was bio-accumulated (with 1.26 in Nile tilapia), while other radionuclides (²²⁶Ra, ²²⁸Ra) were not bio-accumulated; (vi) the radionuclide transfer from water to fish was higher compared to the radionuclide transfer from sediment to fish; (vii) the human effective doses due to consumption of Nile tilapia and Manyara tilapia were 0.00973 and 0.005 mSv/y, respectively, which is below the 1 mSv/y international limit. These findings therefore show that the current levels of radioactivity in fish in the study area do not pose a significant radiological risk to fish consumers. However, more studies on other types of fish are recommended. Full article

In order to better understand the extent to which global climate variability is linked to the frequency and intensity of heat waves and overall changes in temperature throughout the United States (US), correlations between long-term monthly mean, minimum, and maximum temperatures throughout the contiguous US on the one hand and low-frequency variability of multiple climate indices (CIs) on the other hand are analyzed for the period from 1948 to 2018. The Pearson’s correlation coefficient is used to assess correlation strength, while leave-one-out cross-validation and a bootstrapping technique (p-value) are used to address potential serial and spurious correlations and assess the significance of each correlation. Three parameters defined the sliding windows over which surface temperature and CI values were averaged: window size, lag time between the temperature and CI windows, and the beginning month of the temperature window. A 60-month sliding window size and 0 lag time resulted in the highest correlations overall; beginning months were optimized on an individual site basis. High (r ≥ 0.60) and significant (p-value ≤ 0.05) correlations were identified. The Western Hemisphere Warm Pool (WHWP) and El Niño/Southern Oscillation (ENSO) exhibited the strongest links to temperatures in the western US, tropical Atlantic sea surface temperatures to temperatures in the central US, the WHWP to temperatures throughout much of the eastern US, and atmospheric patterns over the northern Atlantic to temperatures in the Northeast and Southeast. The final results were compared to results from previous studies focused on precipitation and coastal sea levels. Regional consistency was found regarding links between the northern Atlantic and overall weather and coastal sea levels in the Northeast and Southeast as well as on weather in the upper Midwest. Though the MJO and WHWP revealed dominant links with precipitation and temperature, respectively, throughout the West, ENSO revealed consistent links to sea levels and surface temperatures along the West Coast. These results help to focus future research on specific mechanisms of large-scale climate variability linked to US regional climate variability and prediction potential. Full article

Amid global concerns regarding climate change and urbanization, understanding the interplay between land use/land cover (LULC) changes, the urban heat island (UHI) effect, and land surface temperatures (LST) is paramount. This study provides an in-depth exploration of these relationships in the context of the Kamrup Metropolitan District, Northeast India, over a period of 22 years (2000–2022) and forecasts the potential implications up to 2032. Employing a high-accuracy supervised machine learning algorithm for LULC analysis, significant transformations are revealed, including the considerable growth in urban built-up areas and the corresponding decline in cultivated land. Concurrently, a progressive rise in LST is observed, underlining the escalating UHI effect. This association is further substantiated through correlation studies involving the normalized difference built-up index (NDBI) and the normalized difference vegetation index (NDVI). The study further leverages the cellular automata–artificial neural network (CA-ANN) model to project the potential scenario in 2032, indicating a predicted intensification in LST, especially in regions undergoing rapid urban expansion. The findings underscore the environmental implications of unchecked urban growth, such as rising temperatures and the intensification of UHI effects. Consequently, this research stresses the critical need for sustainable land management and urban planning strategies, as well as proactive measures to mitigate adverse environmental changes. The results serve as a vital resource for policymakers, urban planners, and environmental scientists working towards harmonizing urban growth with environmental sustainability in the face of escalating global climate change. Full article

Lake Mead located in the Arizona–Nevada region of the Mohave Dessert is a unique and complex water system whose flow follows that of a warm monomictic lake. Although monomictic lakes experience thermal stratification for almost the entire year with a period of complete mixing, the lake on occasion deviates from this phenomenon, undergoing incomplete turnovers categorized with light stratifications every other year. The prolonged drought and growing anthropogenic activities have the potential to considerably impact the quality of the lake. Lake Mead and by extension the Boulder Basin receive cooler flow from the Colorado River and flow with varying temperatures from the Las Vegas Wash (LVW), which impacts its stratification and complete turnovers. This study analyzes four key water quality parameters (WQPs), namely, total dissolved solids (TDS), total suspended solids (TSS), temperature, and dissolved oxygen (DO), using statistical and spatial analyses to understand their variations in light of the lake stratifications and turnovers to further maintain its overall quality and sustainability. The study also evaluates the impacts of hydrological variables including in and out flows, storage, evaporation, and water surface elevation on the WQPs. The results produced from the analysis show significant levels of TDS, TSS, and temperature from the LVW and Las Vegas Bay regions compared with the Boulder Basin. LVW is the main channel for conveying effluents from several wastewater treatment facilities into the lake. We observed an increase in the levels of TDS, TSS, and temperature water quality in the epilimnion compared with the other layers of the lake. The metalimnion and the hypolimnion layer, however, showed reduced DO due to depletion by algal blooms. We observed statistically significant differences in the WQPs throughout various months, but not in the case for season and year, an indication of relatively consistent variability throughout each season and year. We also observed a no clear trend of influence of outflows and inflows on TDS, temperature, and DO. TSS concentrations in the lake, however, remained constant, irrespective of the inflows and outflows, possibly due to the settling of the sediments and the reservoir capacity. Full article

The AquaCrop model is used to predict rice yield in response to different irrigation management in the Yanyun irrigation area in Yangzhou, China, and the constraints to rice production were identified to maximize water productivity based on model simulations. The model was calibrated by comparing measured and predicted canopy cover (CC), yield, and soil water content during the growing season in 2018. The results showed that, for CC simulations, R² was 0.99, RMSE was 3.6%, and NRMSE was 5.3%; for Biomass simulation, RMSE was 0.50 t/ha, and NRMSE was 5.3%. Different irrigation strategies were analyzed for a long-term simulation period from 1955 to 2014. The simulated rice yield increased rapidly as irrigation demand increased initially, and then gradually stabilized. The simulated rice yield fluctuated in the different years. The Pearson type-III model method was used to identify different hydrological years of wet, normal, and dry years. The analysis identified the wet year as 1991, normal year as 1981, and dry year as 1966. In the different rainfall years (1991, 1981, and 1966) water use efficiency (WUE), water productivity (WPet), and irrigation water productivity (IWP) were utilized to determine the irrigation strategy. The predicted highest WPet in the wet year was 1.77kg m⁻³, while the lowest WPet in the dry year was 1.13 kg m⁻³. The highest IWP was 19.78 kg m⁻³ in the wet year, and 9.32 kg m⁻³ in the normal year; while the lowest IWP in the dry year was 1.90 kg m⁻³. IWP was significantly higher in the rainy year, while WUE was significantly lower. On the other hand, WPet was more extensive in the wet year because the yield was higher, and the Evapotranspiration (ET) was smaller in comparison to the dry year. Full article

Futuristic rainfall projections are used in scale and various climate impact assessments. However, the influence of climate variability on spatial distribution patterns and characteristics of rainfall at the local level, especially in semi-arid catchments that are highly variable and are not well explored. In this study, we explore the influence of climate variability on the spatial distribution and rainfall characteristics at a local scale in the semi-arid Shashe catchment, Northeastern Botswana. The LARS-WG, Long Ashton Research Station Weather Generator downscaling method, three representative scenarios (RCP 2.6, RCP 4.5, and RCP 4.5), three trend detection methods (Mann-Kendall, Sen’s slope, and innovative trend analysis) and L-moment method were used to assess climate change impacts on rainfall. Two data sets were used; one with 40 years of observed data from 1981–2020 and the other with 70 years from 1981–2050 (40 years of observed and 30 years of projected data from 2021–2050). Generally, the study found trend inconsistencies for all the trend detection methods. In most cases, Sen’s Slope has a high estimate of observed and RCP 2.6, while ITA overestimates rainfall totals under RCP 4.5 and RCP 8.5. The trend is increasing for annual total rainfall in most gauging stations while decreasing for annual maximum rainfall. The catchment is homogeneous, and Generalized Logistic distribution is the dataset’s best-fit distribution. Spatial coverage of a 100-year rainfall between 151–180 mm will be 81% based on observed data and 87% based on projected data under RCP 2.6 scenario when it happens. A 200-year rainfall between 196–240 mm under RCP 4.5 and 8.5 has high spatial areal coverage, at least 90% of the total catchment. The outcomes of this study will provide insightful information for water resource management and flood risk assessment under climate change. There is a need, however, to assess the transferability of this approach to other catchments in the country and assess the performance of other advanced modelling systems, such as machine learning, in this region. Full article

The reintroduction of Eurasian beaver (Castor fiber L.) results in significant changes in ecosystems. The purpose of this study is to assess the impact of the environment-forming activity of C. fiber on the riparian phytocoenoses of the Raifa forest sector of the Volga-Kama State Nature Biosphere Reserve (Middle Volga region, European Russia) after the reintroduction. Phytoindication methods of ecological–coenotic groups and indicator values were used to assess changes in environmental conditions under the influence of beaver activity. The influence of the beaver reintroduction factor on the increase in the moisture regime (by three points according to the Tsyganov indicator values) and the illumination of habitats, the richness of soils in nitrogen, and the acidity and salt regime of soils (by one point) was revealed. Under the conditions of fodder and construction activities of the beaver, an increase in the proportion of aquatic and wetland groups from 10.2% to 28.2% and boreal plant species from 15.0% to 27.6% was detected. An expansive nature of the change in the degree of landscape occupancy with wetland plants was noted. A decrease in the degree of landscape occupancy (3 to 2 points) of the distribution of ruderal species in the riparian zones of the waterbodies of the reserve due to the activity of the beaver was revealed. Based on phytoindication and ecological–coenotic analyses, it was shown that the reintroduction of C. fiber into the waterbodies of the Raifa forest sector of the reserve is responsible for maintaining the necessary microclimatic conditions for the preservation of natural southern boreal communities. The results obtained can be used for predictive assessment of the influence of the beaver on riparian (small rivers and lakes) plant communities of forest ecosystems in the Middle Volga region of European Russia and other regions of the planet with similar environmental conditions. Full article

The Lake Victoria basin’s expanding population is heavily reliant on rainfall and river flow to meet their water needs, making them extremely vulnerable to changes in climate and land use. To develop adaptation and mitigation strategies to climate changes it is urgently necessary to evaluate the impacts of climate change on the quantity of water in the rivers that drain into Lake Victoria. In this study, the semi-distributed hydrological SWAT model was used to evaluate the impact of current land use and climate changes for the period of 1990–2019 and assess the probable future impacts of climate changes in the near future (2030–2060) on the Simiyu river discharge draining into Lake Victoria, Northern Tanzania. The General Circulation Model under RCPs 4.5, 6.0 and 8.5 predicted an increase in the annual average temperature of 1.4 °C in 2030 to 2 °C in 2060 and an average of 7.8% reduction in rainfall in the catchment. The simulated river discharge from the hydrological model under RCPs 4.5, 6.0 and 8.5 revealed a decreasing trend in annual average discharge by 1.6 m³/s from 5.66 m³/s in 2019 to 4.0 m³/s in 2060. The increase in evapotranspiration caused by the temperature increase is primarily responsible for the decrease in river discharge. The model also forecasts an increase in extreme discharge events, from a range between 32.1 and 232.8 m³/s in 1990–2019 to a range between 10.9 and 451.3 m³/s in the 2030–2060 period. The present combined impacts of climate and land use changes showed higher effects on peak discharge at different return periods (Q5 to Q100) with values of 213.7 m³/s (Q5), 310.2 m³/s (Q25) and 400.4 m³/s (Q100) compared to the contributions of climate-change-only scenario with peak discharges of 212.1 m³/s (Q5), 300.2 m³/s (Q25) and 390.2 m³/s (Q100), and land use change only with peak discharges of 295.5 m³/s (Q5), 207.1 m³/s Q25) and 367.3 m³/s (Q100). However, the contribution ratio of climate change was larger than for land use change. The SWAT model proved to be a useful tool for forecasting river discharge in complex semi-arid catchments draining towards Lake Victoria. These findings highlight the need for catchment-wide water management plans in the Lake Victoria Basin. Full article

This study provides, to the best of our knowledge, the first detailed analysis of how surface oil modifies air–sea interactions in a two-way coupled model, i.e., the coupled–ocean–atmosphere–wave–sediment–transport (COAWST) model, modified to account for oil-related changes in air–sea fluxes. This study investigates the effects of oil on surface roughness, surface wind, surface and near-surface temperature differences, and boundary-layer stability and how those conditions ultimately affect surface stress. We first conducted twin-coupled modeling simulations with and without the influence of oil over the Deepwater Horizon (DWH) oil spill period (20 April to 5 May 2010) in the Gulf of Mexico. Then, we compared the results by using a modularized flux model with parameterizations selected to match those selected in the coupled model adapted to either ignore or account for different atmospheric/oceanic processes in calculating surface stress. When non-oil inputs to the bulk formula were treated as being unchanged by oil, the surface stress changes were always negative because of oil-related dampening of the surface roughness alone. However, the oil-related changes to 10 m wind speeds and boundary-layer stability were found to play a dominant role in surface stress changes relative to those due to the oil-related surface roughness changes, highlighting that most of the changes in surface stress were due to oil-related changes in wind speed and boundary-layer stability. Finally, the oil-related changes in surface stress due to the combined oil-related changes in surface roughness, surface wind, and boundary-layer stability were not large enough to have a major impact on the surface current and surface oil transport, indicating that the feedback from the surface oil to the surface oil movement itself is insignificant in forecasting surface oil transport unless the fractional oil coverage is much larger than the value found in this study. Full article